25 realistic Hazardous Materials practice questions for New Mexico CDL applicants. Required for: Drivers transporting placarded hazardous materials. Official test: 30 questions, 24 correct to pass.
Question 1 of 25 · Shipping Papers
Which of these documents must accompany the HazMat?
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A.
Shipping papers
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B.
Hazard placards
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C.
Emergency response info
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D.
All of the above
Correct answer: D.
Shipping papers, placards, and emergency info must all accompany the load.
Question 2 of 25 · Placards
How many sides of a HazMat vehicle must be placarded?
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A.
One
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B.
Two
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C.
Three
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D.
Four
Correct answer: D.
Placards must be displayed on all four sides of the vehicle.
Question 3 of 25 · HazMat Basics
How many hazard classes are there?
Correct answer: C.
There are nine UN hazard classes used for HazMat transportation.
Question 4 of 25 · Placards
Green placards usually indicate:
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A.
Compressed gases (non-flammable)
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B.
Explosives
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C.
Poisons
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D.
Corrosives
Correct answer: A.
Green placards usually indicate non-flammable compressed gases.
Question 5 of 25 · HazMat Driving
Drivers transporting Division 1.1, 1.2, or 1.3 explosives may NOT:
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A.
Take a route that goes through tunnels prohibiting explosives
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B.
Refuel at any station
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C.
Travel during business hours
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D.
Cross any state line
Correct answer: A.
Avoid tunnels and routes prohibiting explosives. Use only approved routes.
Question 6 of 25 · Emergencies
Which of these is the best advice if you have a HazMat leak?
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A.
Continue to the destination
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B.
Stop, secure the area, communicate the danger, get help
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C.
Try to repair it yourself
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D.
Cover the leak
Correct answer: B.
Stop, secure, communicate, and get qualified help. Don't try to handle leaks yourself.
Question 7 of 25 · Placards
When must placards be displayed?
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A.
Before the vehicle is loaded
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B.
Once the HazMat is loaded and secured before driving
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C.
After the trip ends
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D.
Only at weigh stations
Correct answer: B.
Drivers must placard once HazMat is loaded and verify before moving the vehicle.
Question 8 of 25 · Loading
What is "compatibility group letter"?
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A.
A code that tells which explosives can be loaded together
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B.
A type of placard
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C.
A type of vehicle
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D.
A type of safety vest
Correct answer: A.
Letters such as "A," "B," etc., classify explosives that can be transported together.
Question 9 of 25 · Loading
What does "blasting agents" refer to?
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A.
Materials used to detonate explosives
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B.
A class of explosives sensitive to ignition
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C.
Cleaning agents
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D.
Aerosol propellants
Correct answer: A.
Blasting agents are materials designed to be set off using a detonator.
Question 10 of 25 · Loading
Which of these can never be hauled with explosives?
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A.
Cyanides or other toxic substances
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B.
Building materials
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C.
Foodstuffs
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D.
Newspapers
Correct answer: A.
Cyanides, certain other poisons, and other incompatible substances cannot be loaded with explosives.
Question 11 of 25 · Loading
What does the term "marking" refer to?
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A.
Marking the shipper's name on the package
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B.
Putting the proper shipping name and ID number on the package
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C.
Marking the truck's plates
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D.
Marking the route on a map
Correct answer: B.
Marking includes the proper shipping name and the four-digit ID number on the package.
Question 12 of 25 · HazMat Driving
What should a driver do before transporting any HazMat shipment?
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A.
Inspect the placards and shipping papers
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B.
Inspect the vehicle and cargo
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C.
Plan the route
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D.
All of the above
Correct answer: D.
Verify all paperwork, vehicle, cargo, and route before HazMat transport.
Question 13 of 25 · Shipping Papers
HazMat shipping papers must be:
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A.
Out of the driver's reach
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B.
Within the driver's reach while driving and clearly distinguished from other shipping papers
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C.
In the trailer with the cargo
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D.
Mailed to the receiver in advance
Correct answer: B.
Shipping papers must be within reach and identifiable. They must be on the seat or in a door pouch.
Question 14 of 25 · Shipping Papers
Where can a driver find information about which HazMat are flammable?
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A.
Hazardous Materials Table
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B.
CDL test only
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C.
Engine manual
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D.
Driver license documents
Correct answer: A.
The DOT Hazardous Materials Table classifies materials and lists handling requirements.
Question 15 of 25 · Loading
You should turn off your engine when:
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A.
Loading or unloading flammable liquids
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B.
Driving on a hill
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C.
Inspecting brakes
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D.
Refueling on the highway
Correct answer: A.
Turn off the engine when loading or unloading flammable liquids to reduce ignition risk.
Question 16 of 25 · Loading
Which of the following must NEVER be transported with a HazMat shipment?
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A.
Routine cargo
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B.
Other foods
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C.
Class A or B explosives without segregation tables
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D.
Pet food
Correct answer: C.
Explosives have strict segregation rules. Always consult the segregation table.
Question 17 of 25 · Rail Crossings
When approaching railroad crossings hauling HazMat, you should:
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A.
Stop within 15-50 feet of the nearest rail
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B.
Stop only at marked crossings
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C.
Slow down only
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D.
Speed up to clear quickly
Correct answer: A.
Stop 15 to 50 feet from nearest rail. Don't shift gears while crossing.
Question 18 of 25 · Hours of Service
Drivers transporting hazardous materials must keep a written record of duty status because:
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A.
It's a federal regulation for HazMat operations
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B.
Insurance requires it
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C.
It looks professional
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D.
Drivers don't need to keep records
Correct answer: A.
Federal hours-of-service rules apply to HazMat drivers as to other CMV drivers.
Question 19 of 25 · Rail Crossings
What is the maximum stopping distance allowed for HazMat vehicles approaching a railroad crossing?
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A.
Stop within 15-50 feet of the nearest rail and not closer than 15 feet
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B.
Stop on the tracks
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C.
Stop only when train is approaching
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D.
No stop required
Correct answer: A.
HazMat vehicles must stop 15 to 50 feet from the nearest rail before crossing.
Question 20 of 25 · Placards
Which of these placards has a yellow background?
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A.
Flammable solids
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B.
Oxidizers
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C.
Corrosives
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D.
Radioactive
Correct answer: B.
Yellow background placards typically indicate oxidizers.
Question 21 of 25 · CDL Rules
What does the letter "H" represent on a CDL?
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A.
Hazardous materials endorsement
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B.
Heavy vehicle endorsement
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C.
Highway driving endorsement
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D.
Hauling endorsement
Correct answer: A.
The H endorsement allows a CDL holder to transport placarded hazardous materials.
Question 22 of 25 · Loading
What is "containment"?
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A.
Putting HazMat in proper packaging
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B.
A type of placard
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C.
Stopping leaks during transport
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D.
Containing fumes inside the trailer
Correct answer: A.
Containment means using packaging that meets DOT specifications for the material being shipped.
Question 23 of 25 · Tank Operations
What does the term "outage" mean in HazMat tank operations?
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A.
Loss of electrical power
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B.
Empty space left in a tank to allow for liquid expansion
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C.
Out-of-service tank
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D.
A leak in the tank
Correct answer: B.
Outage is the empty space left for liquid expansion due to temperature changes.
Question 24 of 25 · Parking
When can a HazMat shipment be left unattended?
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A.
Whenever the driver leaves the vehicle
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B.
Only in safe locations such as a carrier facility
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C.
Anywhere with a sign
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D.
Only on private roads
Correct answer: B.
HazMat must be attended unless parked at a carrier facility or other approved location.
Question 25 of 25 · Placards
What does the placard table tell you?
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A.
Which placards are required for which materials and quantities
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B.
Vehicle dimensions
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C.
Highway routes
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D.
Loading dock procedures
Correct answer: A.
The placarding table sets the placard rules based on hazard class and amount.
About the Hazardous Materials Test
The Hazardous Materials (HazMat) test covers the rules for transporting materials that pose a risk to health, safety, and property. Topics include the hazardous materials table, shipping papers, marking, labeling, placarding, loading and unloading, bulk packaging, driving and parking rules, communications, emergencies, and hazardous materials regulations enforced by the U.S. Department of Transportation Pipeline and Hazardous Materials Safety Administration. A federal Transportation Security Administration (TSA) background check is also required.
The New Mexico Motor Vehicle Division administers this knowledge test as part of its commercial driver license program. To earn the HazMat Endorsement (H) on your New Mexico CDL, you need to score at least 24 out of 30 on the official version.
Topics covered on this practice test
- Loading: 7 questions
- Placards: 5 questions
- Shipping Papers: 3 questions
- HazMat Driving: 2 questions
- Rail Crossings: 2 questions
- HazMat Basics: 1 question
- Emergencies: 1 question
- Hours of Service: 1 question
- CDL Rules: 1 question
- Tank Operations: 1 question
- Parking: 1 question
How to use this practice test
- Read each question carefully. CDL questions are written precisely — small wording differences matter.
- Click "Show Answers & Explanations" only after answering every question. Don't peek mid-test.
- Read the explanation for every question, even ones you got right. The reasoning is more important than the answer.
- Repeat the test until you score 100%. The questions are deterministic per state, so you can track your improvement over multiple sessions.
- Move on to the other endorsement tests for New Mexico until you're ready for the official exam.
Tips specific to the Hazardous Materials test
HazMat is the longest knowledge test (30 questions) and adds a Transportation Security Administration (TSA) background check. Most candidates struggle with placard colors, the segregation table, shipping paper requirements, and emergency response procedures. Use the official Emergency Response Guidebook (ERG) alongside this practice set.