25 realistic Hazardous Materials practice questions for Arizona CDL applicants. Required for: Drivers transporting placarded hazardous materials. Official test: 30 questions, 24 correct to pass.
Question 1 of 25 · Shipping Papers
Where must HazMat shipping papers be kept while loading or unloading?
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A.
In the cab only
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B.
On the dock with the cargo
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C.
On the seat of the cab or in a door pouch within reach
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D.
Locked in the glove box
Correct answer: C.
Papers must be readily accessible at all times during transport.
Question 2 of 25 · HazMat Basics
What is "hazard class"?
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A.
A grouping of materials by hazard type
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B.
A type of placard
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C.
A required driving license
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D.
A type of HazMat trailer
Correct answer: A.
There are nine hazard classes that group materials with similar dangers.
Question 3 of 25 · Loading
You should turn off your engine when:
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A.
Loading or unloading flammable liquids
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B.
Driving on a hill
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C.
Inspecting brakes
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D.
Refueling on the highway
Correct answer: A.
Turn off the engine when loading or unloading flammable liquids to reduce ignition risk.
Question 4 of 25 · HazMat Basics
How many hazard classes are there?
Correct answer: C.
There are nine UN hazard classes used for HazMat transportation.
Question 5 of 25 · Placards
Which placard color usually means a flammable material?
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A.
Red
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B.
Yellow
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C.
Green
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D.
Blue
Correct answer: A.
Red typically indicates flammable materials.
Question 6 of 25 · Hours of Service
Drivers transporting hazardous materials must keep a written record of duty status because:
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A.
It's a federal regulation for HazMat operations
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B.
Insurance requires it
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C.
It looks professional
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D.
Drivers don't need to keep records
Correct answer: A.
Federal hours-of-service rules apply to HazMat drivers as to other CMV drivers.
Question 7 of 25 · Shipping Papers
HazMat shipping papers must be:
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A.
Out of the driver's reach
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B.
Within the driver's reach while driving and clearly distinguished from other shipping papers
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C.
In the trailer with the cargo
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D.
Mailed to the receiver in advance
Correct answer: B.
Shipping papers must be within reach and identifiable. They must be on the seat or in a door pouch.
Question 8 of 25 · Emergencies
When must drivers inform the carrier and emergency responders during a HazMat emergency?
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A.
As soon as it's safe to do so
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B.
When they reach the destination
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C.
Only after the cargo is unloaded
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D.
Only if asked
Correct answer: A.
Notify carrier and authorities immediately as soon as you can safely do so.
Question 9 of 25 · Loading
Which of the following must NEVER be transported with a HazMat shipment?
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A.
Routine cargo
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B.
Other foods
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C.
Class A or B explosives without segregation tables
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D.
Pet food
Correct answer: C.
Explosives have strict segregation rules. Always consult the segregation table.
Question 10 of 25 · CDL Rules
What does the letter "H" represent on a CDL?
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A.
Hazardous materials endorsement
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B.
Heavy vehicle endorsement
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C.
Highway driving endorsement
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D.
Hauling endorsement
Correct answer: A.
The H endorsement allows a CDL holder to transport placarded hazardous materials.
Question 11 of 25 · Parking
When parking HazMat overnight, you should:
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A.
Park near homes
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B.
Choose well-lit, safe areas away from people and buildings
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C.
Park on the shoulder of any road
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D.
Park in residential areas
Correct answer: B.
Use safe, well-lit parking areas away from people and buildings.
Question 12 of 25 · Security
Drivers should report any HazMat shipment that:
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A.
Appears to be tampered with
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B.
Has missing or damaged placards
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C.
Has a strong odor or evidence of leakage
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D.
All of the above
Correct answer: D.
Always report any sign of tampering, damaged placards, or leak evidence.
Question 13 of 25 · Placards
What does the placard table tell you?
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A.
Which placards are required for which materials and quantities
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B.
Vehicle dimensions
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C.
Highway routes
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D.
Loading dock procedures
Correct answer: A.
The placarding table sets the placard rules based on hazard class and amount.
Question 14 of 25 · Placards
What does each placard show?
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A.
The hazard class number
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B.
A pictorial symbol for the hazard
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C.
The four-digit ID number when required
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D.
All of the above
Correct answer: D.
Placards show the hazard class number, symbol, and ID number when required.
Question 15 of 25 · HazMat Basics
Which HazMat is most dangerous if released into the environment?
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A.
Class 7 radioactive
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B.
Class 4 flammable solid
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C.
All HazMat are dangerous and require precaution
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D.
Class 9 miscellaneous
Correct answer: C.
Treat every HazMat shipment as dangerous and follow all rules.
Question 16 of 25 · Placards
Placards are warning signs placed on:
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A.
Drivers' shirts
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B.
The outside of vehicles transporting HazMat
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C.
The shipping papers only
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D.
Inside the cab
Correct answer: B.
Diamond-shaped placards on the four sides of the vehicle warn others of hazardous cargo.
Question 17 of 25 · Emergencies
Drivers must report HazMat incidents to:
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A.
The local newspaper
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B.
Carrier and law enforcement, then the National Response Center
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C.
No one — drivers are not responsible
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D.
The shipper only
Correct answer: B.
Notify your carrier and local responders, then call the National Response Center if reportable.
Question 18 of 25 · Loading
Which of these can never be hauled with explosives?
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A.
Cyanides or other toxic substances
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B.
Building materials
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C.
Foodstuffs
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D.
Newspapers
Correct answer: A.
Cyanides, certain other poisons, and other incompatible substances cannot be loaded with explosives.
Question 19 of 25 · HazMat Driving
Drivers transporting Division 1.1, 1.2, or 1.3 explosives may NOT:
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A.
Take a route that goes through tunnels prohibiting explosives
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B.
Refuel at any station
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C.
Travel during business hours
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D.
Cross any state line
Correct answer: A.
Avoid tunnels and routes prohibiting explosives. Use only approved routes.
Question 20 of 25 · Placards
How many sides of a HazMat vehicle must be placarded?
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A.
One
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B.
Two
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C.
Three
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D.
Four
Correct answer: D.
Placards must be displayed on all four sides of the vehicle.
Question 21 of 25 · Placards
Which of these is required if a vehicle's placards are missing or destroyed?
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A.
Placards must be replaced before continuing
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B.
Drivers can continue without placards
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C.
Drivers must call OSHA
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D.
Drivers must wait until next shipping point
Correct answer: A.
Replace missing or damaged placards immediately before continuing.
Question 22 of 25 · Emergencies
When a HazMat package leaks, you should:
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A.
Move it to a safe area
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B.
Secure the area and call for help
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C.
Continue the trip
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D.
Place it in the trailer's rear
Correct answer: B.
Don't move leaking packages. Secure the area and contact qualified responders.
Question 23 of 25 · Shipping Papers
What information must a HazMat driver have on the bills of lading?
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A.
Total quantity by weight or volume
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B.
Number and type of packages
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C.
Shipping name and hazard class
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D.
All of the above
Correct answer: D.
All of these must be included for HazMat shipments.
Question 24 of 25 · HazMat Driving
What is the speed limit when transporting HazMat through a tunnel?
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A.
Tunnel speed limit minus 10 mph
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B.
Posted limit
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C.
No speed limit applies to HazMat
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D.
Posted speed unless lower limit is posted for HazMat
Correct answer: D.
Follow posted limits; lower limits often apply specifically to HazMat in tunnels.
Question 25 of 25 · Placards
Yellow placards generally indicate:
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A.
Flammable solids
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B.
Oxidizers
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C.
Corrosives
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D.
Radioactive materials
Correct answer: B.
Yellow placards usually indicate oxidizers.
About the Hazardous Materials Test
The Hazardous Materials (HazMat) test covers the rules for transporting materials that pose a risk to health, safety, and property. Topics include the hazardous materials table, shipping papers, marking, labeling, placarding, loading and unloading, bulk packaging, driving and parking rules, communications, emergencies, and hazardous materials regulations enforced by the U.S. Department of Transportation Pipeline and Hazardous Materials Safety Administration. A federal Transportation Security Administration (TSA) background check is also required.
The Arizona Motor Vehicle Division administers this knowledge test as part of its commercial driver license program. To earn the HazMat Endorsement (H) on your Arizona CDL, you need to score at least 24 out of 30 on the official version.
Topics covered on this practice test
- Placards: 7 questions
- Shipping Papers: 3 questions
- HazMat Basics: 3 questions
- Loading: 3 questions
- Emergencies: 3 questions
- HazMat Driving: 2 questions
- Hours of Service: 1 question
- CDL Rules: 1 question
- Parking: 1 question
- Security: 1 question
How to use this practice test
- Read each question carefully. CDL questions are written precisely — small wording differences matter.
- Click "Show Answers & Explanations" only after answering every question. Don't peek mid-test.
- Read the explanation for every question, even ones you got right. The reasoning is more important than the answer.
- Repeat the test until you score 100%. The questions are deterministic per state, so you can track your improvement over multiple sessions.
- Move on to the other endorsement tests for Arizona until you're ready for the official exam.
Tips specific to the Hazardous Materials test
HazMat is the longest knowledge test (30 questions) and adds a Transportation Security Administration (TSA) background check. Most candidates struggle with placard colors, the segregation table, shipping paper requirements, and emergency response procedures. Use the official Emergency Response Guidebook (ERG) alongside this practice set.