25 realistic Hazardous Materials practice questions for Missouri CDL applicants. Required for: Drivers transporting placarded hazardous materials. Official test: 30 questions, 24 correct to pass.
Question 1 of 25 · Emergency Equipment
Which of the following is a sign of a tire fire?
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A.
Smoke from the tire
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B.
A loud noise
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C.
Vibration in the steering
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D.
All of the above
Correct answer: D.
Watch for smoke, noise, and vibration as warning signs of a tire fire.
Question 2 of 25 · HazMat Driving
Which is true about smoking near HazMat vehicles?
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A.
Smoking is fine while driving
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B.
Smoking is prohibited within 25 feet of certain materials
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C.
Smoking is allowed at truck stops
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D.
Smoking is allowed in residential areas
Correct answer: B.
Smoking is forbidden within 25 feet of explosives, oxidizers, and flammables.
Question 3 of 25 · Emergency Equipment
Which type of fire is most likely to occur with HazMat?
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A.
Tire fires
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B.
Electrical fires
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C.
Engine compartment fires
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D.
All of the above
Correct answer: D.
Any of these can occur — pre-trip and en-route inspections reduce risk.
Question 4 of 25 · Parking
Some HazMat vehicles cannot be parked within how many feet of a bridge, tunnel, or building?
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A.
100 feet
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B.
200 feet
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C.
300 feet
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D.
500 feet
Correct answer: C.
Class 1 (explosives) generally must not be parked within 300 feet of bridges, tunnels, or buildings.
Question 5 of 25 · Loading
What is "containment"?
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A.
Putting HazMat in proper packaging
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B.
A type of placard
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C.
Stopping leaks during transport
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D.
Containing fumes inside the trailer
Correct answer: A.
Containment means using packaging that meets DOT specifications for the material being shipped.
Question 6 of 25 · Placards
Yellow placards generally indicate:
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A.
Flammable solids
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B.
Oxidizers
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C.
Corrosives
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D.
Radioactive materials
Correct answer: B.
Yellow placards usually indicate oxidizers.
Question 7 of 25 · Shipping Papers
Which of these documents must accompany the HazMat?
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A.
Shipping papers
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B.
Hazard placards
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C.
Emergency response info
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D.
All of the above
Correct answer: D.
Shipping papers, placards, and emergency info must all accompany the load.
Question 8 of 25 · Parking
When can a HazMat shipment be left unattended?
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A.
Whenever the driver leaves the vehicle
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B.
Only in safe locations such as a carrier facility
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C.
Anywhere with a sign
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D.
Only on private roads
Correct answer: B.
HazMat must be attended unless parked at a carrier facility or other approved location.
Question 9 of 25 · HazMat Driving
What should a driver do before transporting any HazMat shipment?
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A.
Inspect the placards and shipping papers
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B.
Inspect the vehicle and cargo
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C.
Plan the route
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D.
All of the above
Correct answer: D.
Verify all paperwork, vehicle, cargo, and route before HazMat transport.
Question 10 of 25 · Rail Crossings
When approaching railroad crossings hauling HazMat, you should:
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A.
Stop within 15-50 feet of the nearest rail
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B.
Stop only at marked crossings
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C.
Slow down only
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D.
Speed up to clear quickly
Correct answer: A.
Stop 15 to 50 feet from nearest rail. Don't shift gears while crossing.
Question 11 of 25 · Shipping Papers
What information must a HazMat driver have on the bills of lading?
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A.
Total quantity by weight or volume
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B.
Number and type of packages
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C.
Shipping name and hazard class
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D.
All of the above
Correct answer: D.
All of these must be included for HazMat shipments.
Question 12 of 25 · Loading
You should turn off your engine when:
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A.
Loading or unloading flammable liquids
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B.
Driving on a hill
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C.
Inspecting brakes
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D.
Refueling on the highway
Correct answer: A.
Turn off the engine when loading or unloading flammable liquids to reduce ignition risk.
Question 13 of 25 · Placards
Which placard color usually means a flammable material?
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A.
Red
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B.
Yellow
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C.
Green
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D.
Blue
Correct answer: A.
Red typically indicates flammable materials.
Question 14 of 25 · Loading
What does "blasting agents" refer to?
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A.
Materials used to detonate explosives
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B.
A class of explosives sensitive to ignition
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C.
Cleaning agents
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D.
Aerosol propellants
Correct answer: A.
Blasting agents are materials designed to be set off using a detonator.
Question 15 of 25 · Emergencies
What should you do if HazMat spills on the ground?
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A.
Cover with sand or absorbent material
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B.
Drive away from the spill
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C.
Get qualified help to handle the spill
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D.
Wash it down with water
Correct answer: C.
Get trained responders. Don't cover, push, or wash the spill yourself.
Question 16 of 25 · Loading
Which of the following must NEVER be transported with a HazMat shipment?
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A.
Routine cargo
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B.
Other foods
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C.
Class A or B explosives without segregation tables
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D.
Pet food
Correct answer: C.
Explosives have strict segregation rules. Always consult the segregation table.
Question 17 of 25 · HazMat Basics
What is "hazard class"?
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A.
A grouping of materials by hazard type
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B.
A type of placard
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C.
A required driving license
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D.
A type of HazMat trailer
Correct answer: A.
There are nine hazard classes that group materials with similar dangers.
Question 18 of 25 · Tank Operations
Which of these are dangers of hauling liquids in tanks?
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A.
Liquid surge
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B.
Outage requirements
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C.
Top-heavy load
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D.
All of the above
Correct answer: D.
Surge, outage, and high center of gravity all make tank vehicles uniquely dangerous.
Question 19 of 25 · CDL Rules
Drivers transporting HazMat must have:
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A.
Only a regular driver license
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B.
A valid CDL with HazMat endorsement and TSA security threat assessment
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C.
A passport
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D.
Physician's certification only
Correct answer: B.
A current CDL with HazMat endorsement (and TSA background check) is required.
Question 20 of 25 · Emergencies
When must drivers inform the carrier and emergency responders during a HazMat emergency?
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A.
As soon as it's safe to do so
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B.
When they reach the destination
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C.
Only after the cargo is unloaded
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D.
Only if asked
Correct answer: A.
Notify carrier and authorities immediately as soon as you can safely do so.
Question 21 of 25 · Shipping Papers
Drivers must check shipping papers for:
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A.
Proper shipping name, hazard class, identification number
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B.
Total quantity
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C.
Emergency response number
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D.
All of the above
Correct answer: D.
Each entry must include the shipping name, class, ID number, quantity, and emergency contact.
Question 22 of 25 · Loading
What does the term "marking" refer to?
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A.
Marking the shipper's name on the package
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B.
Putting the proper shipping name and ID number on the package
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C.
Marking the truck's plates
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D.
Marking the route on a map
Correct answer: B.
Marking includes the proper shipping name and the four-digit ID number on the package.
Question 23 of 25 · Placards
Which of these is required if a vehicle's placards are missing or destroyed?
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A.
Placards must be replaced before continuing
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B.
Drivers can continue without placards
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C.
Drivers must call OSHA
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D.
Drivers must wait until next shipping point
Correct answer: A.
Replace missing or damaged placards immediately before continuing.
Question 24 of 25 · Shipping Papers
How can a driver determine the hazard class of a material?
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A.
Read the shipping paper or check the Hazardous Materials Table
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B.
Smell the package
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C.
Open the container
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D.
Ask other drivers
Correct answer: A.
The hazard class appears on shipping papers; the Hazardous Materials Table is the master reference.
Question 25 of 25 · Placards
What does each placard show?
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A.
The hazard class number
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B.
A pictorial symbol for the hazard
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C.
The four-digit ID number when required
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D.
All of the above
Correct answer: D.
Placards show the hazard class number, symbol, and ID number when required.
About the Hazardous Materials Test
The Hazardous Materials (HazMat) test covers the rules for transporting materials that pose a risk to health, safety, and property. Topics include the hazardous materials table, shipping papers, marking, labeling, placarding, loading and unloading, bulk packaging, driving and parking rules, communications, emergencies, and hazardous materials regulations enforced by the U.S. Department of Transportation Pipeline and Hazardous Materials Safety Administration. A federal Transportation Security Administration (TSA) background check is also required.
The Missouri Department of Revenue — Driver License Bureau administers this knowledge test as part of its commercial driver license program. To earn the HazMat Endorsement (H) on your Missouri CDL, you need to score at least 24 out of 30 on the official version.
Topics covered on this practice test
- Loading: 5 questions
- Placards: 4 questions
- Shipping Papers: 4 questions
- Emergency Equipment: 2 questions
- HazMat Driving: 2 questions
- Parking: 2 questions
- Emergencies: 2 questions
- Rail Crossings: 1 question
- HazMat Basics: 1 question
- Tank Operations: 1 question
- CDL Rules: 1 question
How to use this practice test
- Read each question carefully. CDL questions are written precisely — small wording differences matter.
- Click "Show Answers & Explanations" only after answering every question. Don't peek mid-test.
- Read the explanation for every question, even ones you got right. The reasoning is more important than the answer.
- Repeat the test until you score 100%. The questions are deterministic per state, so you can track your improvement over multiple sessions.
- Move on to the other endorsement tests for Missouri until you're ready for the official exam.
Tips specific to the Hazardous Materials test
HazMat is the longest knowledge test (30 questions) and adds a Transportation Security Administration (TSA) background check. Most candidates struggle with placard colors, the segregation table, shipping paper requirements, and emergency response procedures. Use the official Emergency Response Guidebook (ERG) alongside this practice set.